Bis(imino)phenoxide complexes of zirconium: synthesis, structural characterization and solvent-free ring-opening polymerization of cyclic esters and lactides.
نویسندگان
چکیده
Bis(imino)phenoxide complexes of zirconium possess spectacular reactivity towards the solvent-free polymerization of cyclic ester monomers and lactides. Polymerization of lactide is living and the resulting product has exceptionally high number average molecular weights (Mn). Polymerization of β-butyrolactone gives syndiotactic poly(3-hydroxybutyrate) with good Mn and molecular weight distribution (MWD).
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ورودعنوان ژورنال:
- Dalton transactions
دوره 39 21 شماره
صفحات -
تاریخ انتشار 2010